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11.
Barite-celestite crystals can be synthesized from aqueous solutions during counter-diffusion in a gel column connecting two reservoirs. It is known that such crystals may exhibit oscillatory zoning, whereby the barium composition in the crystal fluctuates more or less regularly from the core of the crystal to its rim. We present here a simple model of oscillatory zoning in such binary solid solutions A1A2 grown from aqueous solutions. The model combines diffusive transport of the relevant ions with an autocatalytic growth process. The latter is formulated as a continuous growth in which the probability of finding a kink site on the growing surface depends on the chemical composition of that surface. Thus, an A1-rich surface favors the growth of A1 over A2, as long as A1 is present in the vicinity of the surface. Precipitation results in a local depletion of A1 in the aqueous solution, and the system may switch to a A2 growth mode, until diffusion replenishes the amount of A1, and so on. We use a dynamical equation for the molar fraction of component A1 in the crystal, which results from mass conservation across the rough crystal-solution interface. Linear stability analysis and direct numerical solutions show that the system exhibits oscillatory behavior. Using the barite-celestite system as a framework, the scaling is consistent with the experimental observations. We discuss the variety of zoning patterns and textures numerically obtained as the concentrations of reactants in the reservoirs vary. This model might help in understanding the formation of oscillatory zoning in hydrothermal environments.  相似文献   
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The withdrawal of the Aral Sea tributaries (Amu and Syr Daria) for cultures has led to significant falls of its level and an important increase in its salinity. During the Holocene, a succession of low and high water inputs occurred. Silty deposits correspond to the high levels and carbonates to the low levels. This study makes a distinction between the Syr Daria and the Amu Daria water inputs during low-level periods by using mineralogical and chemical compositions of the carbonates deposits. Waters from the Syr Daria are more sulphatic and have a low iron content in comparison with that of the Amu Daria. The Syr Daria was the major tributary around 7500, 4956 and 970 yr?BP, whereas around 6200 and 3610 yr?BP, inflow also from the Amu Daria is observed. To cite this article: L. Le Callonnec et al., C. R. Geoscience 337 (2005).  相似文献   
14.
Sea-level return periods are estimated at 18 sites around the English Channel using: (i) the annual maxima method; (ii) the r-largest method; (iii) the joint probability method; and (iv) the revised joint probability method. Tests are undertaken to determine how sensitive these four methods are to three factors which may significantly influence the results; (a) the treatment of the long-term trends in extreme sea level; (b) the relative magnitudes of the tidal and non-tidal components of sea level; and (c) the frequency, length and completeness of the available data. Results show that unless sea-level records with lengths of at least 50 years are used, the way in which the long-term trends is handled in the different methods can lead to significant differences in the estimated return levels. The direct methods (i.e. methods i and ii) underestimate the long (> 20 years) period return levels when the astronomical tidal variations of sea level (relative to a mean of zero) are about twice that of the non-tidal variations. The performance of each of the four methods is assessed using prediction errors (the difference between the return periods of the observed maximum level at each site and the corresponding data range). Finally, return periods, estimated using the four methods, are compared with estimates from the spatial revised joint probability method along the UK south coast and are found to be significantly larger at most sites along this coast, due to the comparatively short records originally used to calibrate the model in this area. The revised joint probability method is found to have the lowest prediction errors at most sites analysed and this method is recommended for application wherever possible. However, no method can compensate for poor data.  相似文献   
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Since Holocene time, above-mean precipitations recorded during the El Niño warm ENSO phase have been linked to the occurrence of severe debris flows in the arid Central Andes. The 2015–2016 El Niño, for its unusual strength, began driving huge and dangerous landslides in the Central Andes (32°) in the recent South Hemisphere summer. The resulting damages negatively impacted the regional economy. Despite this, causes of these dangerous events were ambiguously reported. For this reason, a multidisciplinary study was carried out in the Mendoza River valley. Firstly, a geomorphological analysis of affected basins was conducted, estimating morphometric parameters of recorded events such as velocity, stream flow, and volume. Atmospheric conditions during such events were analyzed, considering precipitations, snow cover, temperature range, and the elevation of the zero isotherm. Based on our findings, the role of El Niño on the slope instability in the Central Andes is more complex in the climate change scenario. Even though some events were effectively triggered by intense summer rainstorm following expectations, the most dangerous events were caused by the progressive uplifting of the zero isotherm in smaller basins where headwaters are occupied by debris rock glaciers. Our research findings give light to the dynamic coupled system ENSO–climate change–landslides (ECCL) at least in this particular case study of the Mendoza River valley. Landslide activity in this Andean region is driven by wetter conditions linked to the ENSO warm phase, but also to progressive warming since the twentieth century in the region. This fact emphasizes the future impact of the natural hazards on Andean mountain communities.  相似文献   
17.
This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.  相似文献   
18.
Aquatic Geochemistry - Spring waters with high-pCO2 content are widely distributed in the Sikhote-Alin region in Russia. Mukhen spa is one such spring located in the northern Sikhote-Alin region....  相似文献   
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Two killifish common in east coast U.S.A. salt marshes,Cyprinodon variegatus Lacepede andFundulus heteroclitus Walbaum, differ in their ability to assimilate nitrogen from and grow on detritus.C. variegatus grew on a diet of detritus ofSpartina alterniflora Loisel, whileF. heteroclitus did not. In addition, when the fish were fed15N-labeledS. alterniflora detritus,15N:14N ratios inC. variegatus were higher than were ratios inF. heteroclitus. Therefore, even though both species ingest large amounts of detritus,C. variegatus makes more effective use of this portion of its diet. These dietary differences are corroborated by anatomical differences that suggest thatC. variegatus should make better use of detrital or plant tissues thanF. heteroclitus. In the label experiment, the degree of label in both fish was directly proportional to the degree of label in the food treatments. In previously published experiments designed to compare plant substrate with attached microbes as nitrogen sources for detritivores, %15N incorporated by a polychaete was also directly proportional to %15N in the detrital food. Therefore, it is difficult to distinguish between plant substrate and microbes as nitrogen sources for this detritivore.  相似文献   
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